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Nonlinear sigma models appear in a wide variety of physics contexts, such as the long-range order with spontaneously broken continuous global symmetries. There are also large classes of quantum criticality admit sigma model descriptions in their phase diagrams without known ultraviolet complete quantum field theory descriptions. We investigate defects in general nonlinear sigma models in any spacetime dimensions, which include the "electric" defects that are characterized by topological interactions on the defects, and the "magnetic" defects that are characterized by the isometries and homotopy groups. We use an analogue of the charge-flux attachment to show that the magnetic defects are in general non-invertible, and the electric and magnetic defects form junctions that combine defects of different dimensions into analogues of higher-group symmetry. We explore generalizations that couple nonlinear sigma models to topological quantum field theories by defect attachment, which modifies the non-invertible fusion and braiding of the defects. We discuss several applications, including constraints on energy scales and scenarios of low energy dynamics with spontaneous symmetry breaking in gauge theories, and axion gauge theories.