论文标题

Na和Ag代替EUCD $ _2 $的磁性和$ T-X $相图为$ _2 $

Magnetism and $T-x$ phase diagrams of Na and Ag substituted EuCd$_2$As$_2$

论文作者

Kuthanazhi, Brinda, Joshi, Kamal R., Ghimire, Sunil, Timmons, Erik, Wang, Lin-Lin, Gati, Elena, Xiang, Li, Prozorov, Ruslan, Bud'ko, Sergey L., Canfield, Paul C.

论文摘要

EUCD $ _2 $ AS $ _2 $是一种反铁磁性半学,可以托管非平凡的拓扑特性,具体取决于其磁性和激发。在这里,我们报告了欧盟的合成和表征(cd $ _ {1-x} $ ag $ _x $)$ _ 2 $ AS $ _2 $和EU $ _ {1-Y} $ na $ _y $ _y $ cd $ _2 $ as $ _2 $,并研究磁性订单的磁性和性质。温度 - 固定相图是根据电阻和磁化率数据构建的。我们观察到将磁过渡分为两个不同的跃迁,并且具有Ag和NA替代的过渡温度之一的逐渐升高。另一个过渡或多或少地独立于掺杂。我们进一步表明,具有净铁磁矩的磁态被Ag和Na掺杂稳定,这可以通过考虑由于替代而导致的频带填充变化来解释,如密度功能理论(DFT)计算所示。因此,我们表明化学替代和随后的带填充变化可能是调整磁接地状态并稳定EUCD $ _2 $中的铁磁相的途径,为$ _2 $。

EuCd$_2$As$_2$ is an antiferromagnetic semimetal, that can host non-trivial topological properties, depending upon its magnetic state and excitations. Here, we report the synthesis and characterization of Eu(Cd$_{1-x}$Ag$_x$)$_2$As$_2$ and Eu$_{1-y}$Na$_y$Cd$_2$As$_2$, and study the evolution and nature of magnetic order with doping. Temperature-substitution phase diagrams are constructed from the electrical resistance and magnetic susceptibility data. We observe a splitting of the magnetic transition into two different transitions, and the gradual increase in one of the transition temperatures with Ag- and Na-substitution. The other transition remains more or less independent of doping. We further show that a magnetic state with a net ferromagnetic moment is stabilized by both Ag and Na doping and this can be explained by considering the changes in band filling due to substitution as suggested by density functional theory (DFT) calculations. We thus show that chemical substitution and the subsequent changes in band filling could be a pathway to tune the magnetic ground state and to stabilize a ferromagnetic phase in EuCd$_2$As$_2$.

扫码加入交流群

加入微信交流群

微信交流群二维码

扫码加入学术交流群,获取更多资源