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In this paper we present an analysis of a chiral anisotropic cosmological scenario from the perspective of quintom fields. In this setup quintessence and phantom fields interact in a non-standard (chiral) way within an anisotropic Bianchi type I background. We present our examination from two fronts: classical and quantum approaches. In the classical program we find analytical solutions given by a particular choice of the emerged relevant parameters. Remarkably, we present an explanation of the ''big-bang'' singularity by means of a ''big-bounce''. Moreover, isotropization is in fact reached as the time evolves. On the quantum counterpart the Wheeler-DeWitt equation is analytically solved for various instances given by the same parameter space from the classical study, and we also include the factor ordering $\rm Q$. Having solutions in this scheme we compute the probability density, which is in effect damped as the volume function and the scalar fields evolve; and it also tends towards a flat FLRW framework when the factor ordering constant $\rm Q \ll 0$. This result might indicate that for a fixed set of parameters, the anisotropies quantum-mechanically vanish for very small values of the parameter $\rm Q$. Finally, classical and quantum solutions reduce to their flat FLRW counterparts when the anisotropies vanish.