论文标题

多孔培养基对多肽溶液的相行为的影响

Effects of porous media on the phase behaviour of polypeptide solutions

论文作者

Shmotolokha, V. I., Holovko, M. F.

论文摘要

作者在先前的作品中提出的多孔介质中各向异性流体的广义范德华方程用于描述多孔培养基对多肽溶液相对相对的影响。通过引入球形剂的潜在井深度和几何参数的温度依赖性,多肽聚($γ$ -Benzyl-$ l $ -Glutamate)(PBLG)的相位行为的主要特征(PBLG)在二甲基甲酰胺溶液中的存在,包括两个nematic相位的存在。结果表明,多孔介质的存在将相图移至较低的密度和较低温度的区域。

The generalized van der Waals equation for anisotropic fluids in porous media, proposed by the authors in previous works, is used to describe the effect of porous media on the phase behavior of polypeptide solutions. By introducing the temperature dependence for the depth of the potential well and the geometric parameters of the spherocylinder, the main features of phase behavior of the polypeptide poly ($γ$-benzyl-$L$-glutamate) (PBLG) in a solution of dimethylformamide, including the existence of two nematic phases, is reproduced. It is shown that the presence of a porous medium shifts the phase diagram to the region of lower densities and lower temperatures.

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