论文标题

热力学材料网络的圆形性:指标,示例和算法

Circularity of Thermodynamical Material Networks: Indicators, Examples, and Algorithms

论文作者

Zocco, Federico

论文摘要

在过去的几年中,向循环经济的过渡已变得越来越重要,因为从长远来看,传统的线性占用措施范式是不可持续的。最近,已经提出了热力学材料网络(TMN)[1]作为设计材料流的一种方法,即任何供应链都可以将任何供应链视为一组可以添加,删除,修改或连接的热力学区室。与良好的材料流量分析(MFA)相比,TMNS利用动力学平衡和普通的微分方程以及通常的质量平衡,因此将循环经济作为一种类似于传统工程设计方法的物质网络设计问题(例如,与热力学周期,电气和水力网络的设计相似),而不是按照储备数据分析数据。因此,TMN允许描绘高度动态的材料库存和流量,其变化可能在不到1分钟内发生;使用MFA实现这种建模准确性将是更多数据密集型。在本文中,我们首先使用基于图形的形式主义制定了TMN的几个循环指标。然后,我们使用两个数值示例来说明它们的计算,用于流体材料的情况,一个数值示例为实体材料而言,为此提供了详细的混合动力学方程和仿真输出。纸质源代码可公开使用。

The transition towards a circular economy has gained importance over the last years since the traditional linear take-make-dispose paradigm is not sustainable in the long term. Recently, thermodynamical material networks (TMNs) [1] have been proposed as an approach to design material flows based on the idea that any supply chain can be seen as a set of thermodynamic compartments that can be added, removed, modified or connected differently. Compared to the well-established material flow analysis (MFA), TMNs leverage dynamical energy balances and ordinary differential equations along with the usual mass balances, thus tackling circular economy as a material network design problem analogous to traditional engineering design approaches (e.g., design of thermodynamic cycles, electrical and hydraulic networks) rather than as an analysis of stock-and-flow data. Hence, TMNs allow the depiction of highly dynamic material stocks and flows whose variations can occur in less than 1 minute; achieving such modelling accuracy with MFA would be more data intensive. In this paper, we first develop several circularity indicators of TMNs using a graph-based formalism. Then, we illustrate their calculation using two numerical examples for the case of fluid materials and one numerical example for the case of solid materials, for which the detailed hybrid dynamical equations and simulation outputs are provided. The paper source code is publicly available.

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