论文标题

ABCB堆叠四边形石墨烯的实验观察

Experimental observation of ABCB stacked tetralayer graphene

论文作者

Wirth, Konstantin G., Profe, Jonas B., Rothstein, Alexander, Kyoseva, Hristiyana, Siebenkotten, Dario, Conrads, Lukas, Klebl, Lennart, Fischer, Ammon, Beschoten, Bernd, Stampfer, Christoph, Kennes, Dante M., Waldecker, Lutz, Taubner, Thomas

论文摘要

在四边形石墨烯中,到目前为止,仅观察到菱形(ABCA)和Bernal(ABAB)堆叠,应该存在三个不等于的层堆叠。三个堆叠序列的电子结构有所不同,由于预计它会在k点附近显示固有的带隙以及本地平坦的频段,因此难以捉摸的第三堆叠(ABCB)是独一无二的。在这里,我们使用散射型扫描近场光学显微镜和共聚焦拉曼显微镜来识别和表征ABCB堆叠的四边形石墨烯的域。我们通过在0.28和0.56 eV之间以幅度和相位分辨的近场纳米光谱镜来解决特征性电导率中的特征间贡献,从而区分了三个堆叠序列。通过将相邻的薄片相互归一化,我们在理论和实验之间实现了良好的一致性,从而使tetralayer石墨烯中ABCB结构域的明确分配。这些结果将近场光谱在带间跃迁中作为半定量工具,从而实现了四边形石墨烯薄片中ABCB结构域的识别,因此为研究这个令人兴奋的阶段的相关物理学提供了基础。

In tetralayer graphene, three inequivalent layer stackings should exist, however, only rhombohedral (ABCA) and Bernal (ABAB) stacking have so far been observed. The three stacking sequences differ in their electronic structure, with the elusive third stacking (ABCB) being unique as it is predicted to exhibit an intrinsic bandgap as well as locally flat bands around the K points. Here, we use scattering-type scanning near-field optical microscopy and confocal Raman microscopy to identify and characterize domains of ABCB stacked tetralayer graphene. We differentiate between the three stacking sequences by addressing characteristic interband contributions in the optical conductivity between 0.28 and 0.56 eV with amplitude and phase-resolved near-field nano-spectroscopy. By normalizing adjacent flakes to each other, we achieve good agreement between theory and experiment, allowing for the unambiguous assignment of ABCB domains in tetralayer graphene. These results establish near-field spectroscopy at the interband transitions as a semi-quantitative tool, enabling the recognition of ABCB domains in tetralyer graphene flakes and therefore, providing a basis to study correlation physics of this exciting phase.

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