论文标题

SMM1:II的益生元分子库存。肽链的基础

The prebiotic molecular inventory of Serpens SMM1: II. The building blocks of peptide chains

论文作者

Ligterink, Niels F. W., Ahmadi, Aida, Luitel, Bijaya., Coutens, Audrey, Calcutt, Hannah, Tychoniec, Łukasz, Linnartz, Harold, Jørgensen, Jes K., Garrod, Robin T., Bouwman, Jordy

论文摘要

这项工作旨在通过在中间质量的原始蛇蛇SMM1-A中搜索这组益生元分子来限制星际酰胺的丰富性。 Alma观察是针对Serpens SMM1进行的。将频谱提取到SMM1-A位置,并使用Cassis Line Analysis软件进行分析,以存在许多酰胺和其他分子的特征旋转线。 nh $ _ {2} $ cho,nh $ _ {2} $ cho $ co $ co $ co $ c {12} $ = 1,nh $ _ {2}^{13} $ cho,ch $ _ {3} $ _ {3} $ c(o) ch $ _ {3} $ c(o)ch $ _ {3} $被牢固地检测到,而trans-nhdcho,nh $ _ {2} $ cdo,ch $ _ {3} $ _ {3} $ nhcho $ nhcho $ν$ = 0,1,ch $ _ {3} $ cooh,以及hoch $ cooh,以及hoch $ cooh,以及hoch $ _} $ _ {2}将这项工作的结果与文献中提出的检测进行了比较。一个统一的ch $ _ {3} $ c(o)nh $ _ {2} $/nh $ _ {2} $ cho比率是针对具有巨大物理差异的一组星际源。基于较小的数据样本,可以看到Ch $ _ {3} $ NHCHO的类似比率。 NH $ _ {2} $ CHO的D/H比率约为1--3 \%,接近低质量源IRAS IRAS中的值〜16293--2422B。 Ch $ _ {3} $ C(O)NH $ _ {2} $和NH $ _ {2} $ CHO的形成可能是链接的。在乌云阶段,这些分子在晶粒表面上形成是一种情况。 NH $ _ {2} $ CHO的高d/h比也被视为表明这些分子是在冰的灰尘晶粒上形成的。直接结果,预计酰胺将存在于行星系统形成的最原始材料中,从而提供益生元材料的储层。

This work aims to constrain the abundances of interstellar amides, by searching for this group of prebiotic molecules in the intermediate-mass protostar Serpens SMM1-a. ALMA observations are conducted toward Serpens SMM1. A spectrum is extracted toward the SMM1-a position and analyzed with the CASSIS line analysis software for the presence of characteristic rotational lines of a number of amides and other molecules. NH$_{2}$CHO, NH$_{2}$CHO $ν_{12}$=1, NH$_{2}^{13}$CHO, CH$_{3}$C(O)NH$_{2}$ $ν$=0,1, CH$_{2}$DOH, CH$_{3}$CHO, and CH$_{3}$C(O)CH$_{3}$ are securely detected, while trans-NHDCHO, NH$_{2}$CDO, CH$_{3}$NHCHO $ν$=0,1, CH$_{3}$COOH, and HOCH$_{2}$CHO are tentatively identified. The results of this work are compared with detections presented in the literature. A uniform CH$_{3}$C(O)NH$_{2}$/NH$_{2}$CHO ratio is found for a group of interstellar sources with vast physical differences. A similar ratio is seen for CH$_{3}$NHCHO, based on a smaller data sample. The D/H ratio of NH$_{2}$CHO is about 1--3\% and is close to values found in the low-mass source IRAS~16293--2422B. The formation of CH$_{3}$C(O)NH$_{2}$ and NH$_{2}$CHO is likely linked. Formation of these molecules on grain surfaces during the dark cloud stage is a likely scenario. The high D/H ratio of NH$_{2}$CHO is also seen as an indication that these molecules are formed on icy dust grains. As a direct consequence, amides are expected to be present in the most pristine material from which planetary systems form, thus providing a reservoir of prebiotic material.

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