论文标题
二维滑动铁电的照片磁化
Photo-magnetization in two-dimensional sliding ferroelectrics
论文作者
论文摘要
轻度互动是理解和操纵材料的几何和电子行为的关键途径之一,尤其是二维材料,由于其高表面与体积比,它们在光学上可以使用。在当前的工作中,我们着重于最近发现的二维滑动铁电材料,其中平面外电化极化可以用一层的水平平移进行切换。结合对称分析和第一原理计算,我们预测光照明可以将非平衡磁矩注入滑动铁电气。这种磁矩由自旋和轨道自由度贡献组成。我们使用$ \ mathrm {zri} _2 $,$ \ mathrm {wte} _2 $,和$ \ mathrm {mos} _2 $ biLayer ferroelectrics来说明我们的理论。在中间的光照射下,在这些系统中,可以在$ 0.1-1 $ $μ_b$上产生非平衡磁矩,这也取决于入射光的极化性质。此外,我们表明,当滑动偶极矩切换时,这种照片注射的磁性会改变其标志。可以通过磁光学方法(例如Kerr或Faraday效应)检测到这种照片,该方法可以用作滑动铁电的指标。因此,可以使用全光泵和探测设置来测量和检测微妙的滑动铁电相。
Light-matter interaction is one of the key routes to understanding and manipulating geometric and electronic behaviors of materials, especially two-dimensional materials which are optically accessible owing to their high surface to volume ratio. In the current work we focus on the recently discovered two-dimensional sliding ferroelectric materials, in which the out-of-plane electric polarization can be switched with a small horizontal translation in one layer. Combining symmetry analysis and first-principles calculations, we predict that light illumination could inject non-equilibrium magnetic moments into the sliding ferroelectrics. Such magnetic moment is composed of both spin and orbital degrees of freedom contributions. We use $\mathrm{ZrI}_2$, $\mathrm{WTe}_2$, and $\mathrm{MoS}_2$ bilayer ferroelectrics to illustrate our theory. Under intermediate light illumination, one can yield non-equilibrium magnetic moments on the order of $0.1-1$ $μ_B$ in these systems, which also depends on the polarization nature of incident light. Furthermore, we show that such photo-injected magnetism changes its sign when the sliding dipole moment switches. This photo-magnetization can be detected by magneto-optical methods (such as Kerr or Faraday effect), which serves as an indicator of sliding ferroelectricity. Hence, one can use an all-optical pump and probe setup to measure and detect the subtle sliding ferroelectric phase.