论文标题

在稀有气体簇上的聚乙烯分子中的激发动力学

Excitation dynamics in polyacene molecules on rare-gas clusters

论文作者

Bohlen, Matthias, Michiels, Rupert, Michelbach, Moritz, Ferchane, Selmane, Walter, Michael, Eisfeld, Alexander, Stienkemeier, Frank

论文摘要

激光诱导的荧光光谱和激发寿命的蒽,四烯和戊季烯分子已在固体氩气簇表面附着的浓度相对于簇大小,分子的密度和激发密度进行了测量。将结果与以前关于附着在霓虹灯簇附着的样品分子的研究进行了比较。讨论了蒽和氩气簇上的寿命行为对比,并提出了解释结果的机制。尽管霓虹灯和氩气簇都被认为是弱相互作用的环境,但我们发现所研究的acCenes的激发衰变动力学显着取决于簇材料。此外,我们发现有关依赖掺杂剂密度的质量差异甚至是定性差异。基于这些观察结果,在新的实验发现的背景下讨论了集体辐射和非辐射衰减机制的先前分配。

Laser-induced fluorescence spectra and excitation lifetimes of anthracene, tetracene, and pentacene molecules attached to the surface of solid argon clusters have been measured with respect to cluster size, density of molecules and excitation density. Results are compared to previous studies on the same sample molecules attached to neon clusters. A contrasting lifetime behavior of anthracene on neon and argon clusters is discussed, and mechanisms are suggested to interpret the results. Although both neon and argon clusters are considered to be weakly interacting environments, we find that the excitation decay dynamics of the studied acenes depends significantly on the cluster material. Moreover, we find even qualitative differences regarding the dependence on the dopant density. Based on these observations, previous assignments of collective radiative and non-radiative decay mechanisms are discussed in the context of the new experimental findings.

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