论文标题
非平衡的非马克维亚系统的相关函数:单个指数内存以外的分析表达式
Correlation functions of non-Markovian systems out of equilibrium: Analytical expressions beyond single-exponential memory
论文作者
论文摘要
本文涉及随机系统与记忆的相关函数,一个突出的例子是分子或胶体穿越复合物(例如粘弹性)流体环境。众所周知,基于非马克维亚随机方程的此类系统的分析研究非常困难。一个常见的近似值是单指数内存的近似值,对应于引入一个辅助变量,该变量耦合到主变量的马尔可夫动力学。作为概括,我们在这里研究了一类具有三个自由度的“玩具”模型,从而产生了更复杂的记忆形式。具体而言,我们主要在分析的基础上考虑,胶体粒子耦合到两个辅助变量的胶体粒子的运动不足和过度阻尼,其中变量之间的耦合可以是互惠或非互联网。投影辅助变量,我们获得了具有摩擦内核和彩色噪声的非马克维亚兰格文方程,它们的结构与广义的langevin方程相似。但是,对于目前的系统,非马克维亚方程可能违反波动散失关系以及详细的平衡,表明该系统不均衡。然后,我们系统地研究了基础马尔可夫系统的耦合拓扑与各种自相关功能之间的联系。我们证明已经两个辅助变量可以产生令人惊讶的复杂(例如,非单调或振动性或振动性)和相关功能。最后,我们表明,具有两个辅助变量和合适的非重点耦合的最小程度过强的模型产生的相关功能类似于描述光学陷阱中流体动力回流的功能。
This paper is concerned with correlation functions of stochastic systems with memory, a prominent example being a molecule or colloid moving through a complex (e.g., viscoelastic) fluid environment. Analytical investigations of such systems based on non-Markovian stochastic equations are notoriously difficult. A common approximation is that of a single-exponential memory, corresponding to the introduction of one auxiliary variable coupled to the Markovian dynamics of the main variable. As a generalization, we here investigate a class of "toy" models with altogether three degrees of freedom, giving rise to more complex forms of memory. Specifically, we consider, mainly on an analytical basis, the under- and overdamped motion of a colloidal particle coupled linearly to two auxiliary variables, where the coupling between variables can be either reciprocal or non-reciprocal. Projecting out the auxiliary variables, we obtain non-Markovian Langevin equations with friction kernels and colored noise, whose structure is similar to that of a generalized Langevin equation. For the present systems, however, the non-Markovian equations may violate the fluctuation-dissipation relation as well as detailed balance, indicating that the systems are out of equilibrium. We then study systematically the connection between the coupling topology of the underlying Markovian system and various autocorrelation functions.We demonstrate that already two auxiliary variables can generate surprisingly complex (e.g., non-monotonic or oscillatory) memory and correlation functions. Finally, we show that a minimal overdamped model with two auxiliary variables and suitable non-reciprocal coupling yields correlation functions resembling those describing hydrodynamic backflow in an optical trap.