论文标题
底物上的纳米聚合物聚合物：一项理论研究
A nano polymer aggregate on a substrate: A Theoretical study
论文作者
论文摘要
我们考虑理想线性聚合物链的晶格模型，以模仿半柔性同型聚合物链的构象。假定聚合物链局限于相当小的面积，因此柔性链构象很容易在纳米区域聚合。已经使用分析计算描述了这种情况可能会导致纳米长度限制大分子限制的半灵性均聚合物大分子的热力学的有趣且独特的理论发现。我们还讨论了由于无限长的理想聚合物链的纳米尺度限制而引起的持续长度和弹性力的特征。
We consider the lattice model for an ideal-linear polymer chain to mimic the conformations of the semi-flexible homo-polymer chain. The polymer chain is assumed to confine in the fairly small area, such that the flexible chain conformations are easily polymerized in the nano-area. It has been described using analytical calculations that such a situation may lead to interesting and distinct theoretical findings of the thermodynamics of semi-flexible homo-polymeric macromolecules where the macromolecules are confined in the nano-length scale. We also discuss the characteristics of the persistent length and the elastic force due to the nano scale confinement of an infinitely long ideal polymer chain.
