论文标题
三元氮化物材料:基本原理和新兴设备应用
Ternary Nitride Materials: Fundamentals and Emerging Device Applications
论文作者
论文摘要
在过去的几十年中,人们对无机三元材料的兴趣迅速增长,因为它们的化学和结构多样性使它们吸引了各种应用。由于N2的稳定性提出的综合挑战,预测的氮化物化合物的数量使那些已合成的氮化物相形见war,这为探索提供了广泛的机会。这篇综述总结了三元氮化物的基本特性和结构化学,利用亚稳定性和氮化学势的影响。关于普遍缺陷的讨论,无论是有害和有益的,都进行了对合成技术的调查及其与亚稳定性的相互作用。在整个综述中,我们重点介绍了三元氮化体具有特殊希望的应用(例如固态照明,电化学能源存储和电子设备)。
Interest in inorganic ternary nitride materials has grown rapidly over the past few decades, as their diversity of chemistries and structures make them appealing for a variety of applications. Due to synthetic challenges posed by the stability of N2, the number of predicted nitride compounds dwarfs those that have been synthesized, offering a breadth of opportunity for exploration. This review summarizes the fundamental properties and structural chemistry of ternary nitrides, leveraging metastability and the impact of nitrogen chemical potential. A discussion of prevalent defects, both detrimental and beneficial, is followed by a survey of synthesis techniques and their interplay with metastability. Throughout the review, we highlight applications (such as solid-state lighting, electrochemical energy storage, and electronic devices) in which ternary nitrides show particular promise.