论文标题

多组分钙钛矿氧化物的2D表面相图:la $ _ {0.8} $ sr $ _ {0.2} $ mno $ _3 $(110)

2D Surface Phase Diagram of a Multicomponent Perovskite Oxide: La$_{0.8}$Sr$_{0.2}$MnO$_3$(110)

论文作者

Franceschi, Giada, Schmid, Michael, Diebold, Ulrike, Riva, Michele

论文摘要

(110)面向灯笼 - 木锰矿(la $ _ {0.8} $ sr $ _ {0.2} $ mno $ _3 $,lsmo)的许多表面重建。减少$μ__\ text {o} $使MN在整个表面上迁移,将相分开为富含A位的区域,并导致各种与组成相关的,结构上多样的B-Site富含B-Site的重建。通过扫描隧道显微镜(STM)量化了这些相分离结构的组成,这些结果用于构建LSMO(110)平衡表面结构的2D相图。

The many surface reconstructions of (110)-oriented lanthanum--strontium manganite (La$_{0.8}$Sr$_{0.2}$MnO$_3$, LSMO) were followed as a function of the oxygen chemical potential ($μ_\text{O}$) and the surface cation composition. Decreasing $μ_\text{O}$ causes Mn to migrate across the surface, enforcing phase separation into A-site-rich areas and a variety of composition-related, structurally diverse B-site-rich reconstructions. The composition of these phase-separated structures was quantified with scanning tunneling microscopy (STM), and these results were used to build a 2D phase diagram of the LSMO(110) equilibrium surface structures.

扫码加入交流群

加入微信交流群

微信交流群二维码

扫码加入学术交流群,获取更多资源