论文标题

不同类别的计算机眼镜的非音调振动光谱的通用性

Universality of the nonphononic vibrational spectrum across different classes of computer glasses

论文作者

Richard, David, González-López, Karina, Kapteijns, Geert, Pater, Robert, Vaknin, Talya, Bouchbinder, Eran, Lerner, Edan

论文摘要

最近已经确定,简单的计算机玻璃模型的低频光谱由柔软的,准定位的非Phononic振动模式填充,其频率$ω$遵循无间隙,通用的分布$ {\ cal d}(ω)\!尽管这种通用的非调音频谱已被证明可以改变玻璃历史和空间维度,但到目前为止,仅在具有径向对称的成对相互作用电位的简单计算机玻璃中观察到它。因此,在简单的计算机眼镜中看到的非调音光谱通用性与现实实验室眼镜的相关性尚不清楚。在这里,我们证明了通用$ω^4 $非光谱频谱在各种逼真的计算机玻璃模型中的出现,范围从具有三体相互作用的四面体网络玻璃,到分子玻璃和玻璃聚合物到块状金属玻璃(BMG)。与先前的观察结果一起,我们的结果表明,从熔体中的任何玻璃固体淬灭的低频非频振动频谱具有通用$ω^4 $定律,独立于其显微镜相互作用的性质。

It has been recently established that the low-frequency spectrum of simple computer glass models is populated by soft, quasilocalized nonphononic vibrational modes whose frequencies $ω$ follow a gapless, universal distribution ${\cal D}(ω)\!\sim\!ω^4$. While this universal nonphononic spectrum has been shown to be robust to varying the glass history and spatial dimension, it has so far only been observed in simple computer glasses featuring radially-symmetric, pairwise interaction potentials. Consequently, the relevance of the universality of nonphononic spectra seen in simple computer glasses to realistic laboratory glasses remains unclear. Here we demonstrate the emergence of the universal $ω^4$ nonphononic spectrum in a broad variety of realistic computer glass models, ranging from tetrahedral network glasses with three-body interactions, through molecular glasses and glassy polymers, to bulk metallic glasses (BMGs). Taken together with previous observations, our results indicate that the low-frequency nonphononic vibrational spectrum of any glassy solid quenched from a melt features the universal $ω^4$ law, independently of the nature of its microscopic interactions.

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